Product ID:DIPHENYLCARBAZONE-BROMOPHENOL BLUE INDICATOR SOLUTION
MSDS Date:04/06/1989
FSC:6810
NIIN:00F023720
MSDS Number: BNJHW

MALLINCKRODT INC

PARIS BYPASS
PARIS, KY 40361
US

Emergency Phone: (606) 987-7000

Info Phone: (606) 987-7000

Cage: 62910

MALLINCKRODT SPECIALTY CHEMICALS CO

PHILLIPSBURG, NJ 08865 US

Telephone: 908-859-2151

Cage: 62910

ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

DIPHENYLCARBAZONE

CAS: 538-62-5

RTECS: LQ9420000

Fraction By Weight: <1%

BROMOPHENOL BLUE

CAS: 115-39-9

RTECS: SJ7453000

Fraction By Weight: <1%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: NOSE/THROAT
IRRITATION/NARCOTIC
EFFECT/DROWSINESS/HEADACHE/STAGGERING/UNCONSCIOUSNESS/DEATH.
INGESTION: DROWSINESS/UNCONSCIOUSNESS/GI
PAIN/CRAMPS/NAUSEA/VOMITING/DIARRHEA/DEATH. SKIN: IRRI
TATION/STINGING EFFECT/BURNING
SENSATION/DRYING/CRACKING/DERMATITIS. EYES: IRRITATION/CORNEAL
BURNS/DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: NOSE/THROAT IRRITATION/NARCOTIC
EFFECT/DROWSINESS/HEADACHE/STAGGERING/UNCONSCIOUSNESS/DEATH.
INGESTION: DROWSINESS/UNCONSCIOUSNESS/GI
PAIN/CRAMPS/NAUSEA/VOMITING/DIARRHEA/DEATH. SKIN: IRRI
TATION/STINGING EFFECT/BURNING
SENSATION/DRYING/CRACKING/DERMATITIS. EYES: IRRITATION/CORNEA
BURNS/DAMAGE.
Medical Cond Aggravated by Exposure:SKIN DISORDERS, EYE PROBLEMS OR
IMPAIRED RESPIRATORY FUNCTION.

First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGESTION: GIVE WATER TO DRINK. INDUCE VOMITING. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SKIN: WASH W/SOAP OR
MILD DETERGENT & WATER FOR AT LEAST 15 MINS. EYES: WASH W/PLENTY OF
WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point Method:CC
Flash Point:53F
Lower Limits:2%
Upper Limits:12%
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, OR CO2.
USE WATER SPRAY TO KEEP FIRE EXPOSED CONTAINERS COOL.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & A NIOSH
APPROVED SCBA W/FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR
OTHER POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:>53F, VAPOR-AIR MIXTURES ARE EXPLOSIVE
W/IN 2-12% LIMITS. CONTACT W/STRONG OXIDIZERS MAY CAUSE
FIRE/EXPLOSION. VAPORS CAN FLOW TO IGNITION SOURCE & FLASHBACK.

Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE AREA.
SMALL: ABSORB ON PAPER TOWELS/EVAPORATE IN A FUME HOOD. ALLOW
ENOUGH TIME FOR FUMES TO CLEAR. LARGE: COLLECT AS WASTE & ATOMIZE
IN A RCRA COMBUSTION CHAMBER OR ABSORB W/VERMICULITE/DRY
SAND/EARTH FOR DISPOSAL.

Handling and Storage Precautions:STORE IN A COOL, DRY WELL-VENTILATED
AREA, AWAY FROM HEAT, SPARKS & FLAME. PROTECT AGAINST PHYSICAL
DAMAGE. OUTSIDE/DETACHED STORAGE IS PREFERRED.
Other Precautions:BOND/GROUND CONTAINERS FOR TRANSFER TO AVOID STATIC
SPARKS. DON'T SMOKE IN STORAGE OR USAGE AREAS. USE NON-SPARKING
TOOLS & EQUIP. AVOID CONTACT W/SKIN, EYES & CLOTHING & BREATHING
VAPOR. KEEP CONTAIN ERS CLOSED. DON'T WEAR CONTACT LENSES.

Respiratory Protection:IF >TLV, USE A NIOSH APPROVED FULL FACEPIECE
CHEMICAL CARTRIDGE RESPIRATOR OR A SUPPLIED AIR FULL FACEPIECE
RESPIRATOR OR AIRLINED HOOD.
Ventilation:LOCAL &/OR GENERAL TO KEEP Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL SAFETY GOGGLES/FULL FACE SHIELD
Other Protective Equipment:BOOTS, LAB COAT, APRON, COVERALLS, EYE WASH
FOUNTAIN & QUICK-DRENCH FACILITIES
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
MATERIALS TO AVOID: POTASSIUM TERT-BUTOXIDE, HYPOCHLOROUS ACID,
ISOCYANATES, NITROFORM, PHOSGENE, OLEUM & PERCHLORIC ACID.

Boiling Pt:B.P. Text:180F
Melt/Freeze Pt:M.P/F.P Text:-128F
Vapor Pres: 33
Vapor Density: 2.1
Spec Gravity: 0.79
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, REDDISH PURPLE SOLUTION W/RUBBING ALCOHOL.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS/ACETADEHYDE/CHLORINE/ETHYLENE
OXIDE/HYDROGEN-PALLADIUM/HYDROGEN PEROXIDE-SULFURIC ACID. SEE
SUPP.
Stability Condition to Avoid:HEAT, SUNLIGHT, FLAME OR OTHER SOURCES OF
IGNITION.
Hazardous Decomposition Products:CO

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. AUTOIGNITION TEMP: 750F. FLAMMABLE LIQUID.

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particular situation.